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We study the crystal structure and the magnetic properties of Ba1−xBixTi0.9Fe0.1O3 (0  x  0.12) ceramics prepared by using a conventional solid-state reaction. X-ray diffraction and Raman scattering spectroscopy measurements show that Bi3+ substitution suppresses the formation of the hexagonal BaTiO3 phase and stabilizes the tetragonal BaTiO3 phase. The samples with x  0.08 demonstrate a single tetragonal BaTiO3 phase. Samples with x  0.1 show obvious magnetic orders at room temperature. The saturated magnetization, paramagnetic contribution and magnetic transition temperature are found to depend on the Bi doping concentration. Samples with 0.08  x  0.1 show a single tetragonal phase structure with a ferromagnetic order. These results indicate that the crystal structure and the ferromagnetic properties of Ba1−xBixTi0.9Fe0.1O3 (0  x  0.12) ceramics are intrinsic.