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New two kinds of methacrylate monomers having a benzene ring inserted between spacer and meth-acryloyl group and the chiral center connected to the terminal of the mesogenic structures were synthesized. In these tworegard to the length changes of the spacers and mesogenicgroups were investigated. The first series did not show any liquid crystalline phases in the intermediate compounds norin the end products. However, the methacrylates of second series showed the liquid crystalline phases in the intermediatecompounds as well as in the final products regardless of the length of the spacers.. . . . . . . . . . ... . . . . . . . . . . . . τ .. θ . . . . . . . . . .